Испанийн эртний алтан эдлэлийн цуглуулгаас сансрын гаралтай төмөр олдлоо

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Энэхүү мэдээ, нийтлэлийг хиймэл оюун боловсруулав.

Гурван мянга гаруй жилийн настай археологийн олдворуудаас сансрын солирын төмрөөр хийсэн байж болзошгүй хоёр эд зүйл илрүүлжээ.

1963 оны арванхоёрдугаар сард Испанийн Аликанте мужийн Виллена хотын ойролцоох хайрганы карьерт малтлага хийх явцад хүрэл зэвсгийн үеийн үнэт эдлэлийн асар том цуглуулга олдсон юм. Нийт 66 орчим эд зүйлээс бүрдэх энэхүү “Вилленагийн эрдэнэс” нь ихэвчлэн алт, мөнгө, хув ашиглан бүтээгдсэн бөгөөд МЭӨ 1500-1200 оны үед хамаардаг байна. Гэвч цуглуулга доторх бусад зүйлсээс эрс ялгаатай, зэвэрч гэмтсэн хоёр төмөр эдлэл олон арван жилийн турш эрдэмтдийн анхаарлыг татаж иржээ.

Төмөр эдлэлийн нэг нь 8.5 см диаметртэй бугуйвч, нөгөө нь алтаар чимэглэсэн 4.5 см өргөн хагас бөмбөлөг хэлбэртэй зүйл юм. Иберийн хойгт төмрийн хүдэр боловсруулах технологи МЭӨ 850 орчим жилээс эхэлсэн гэж үздэг тул эдгээр олдвор нь хүрэл зэвсгийн үеийн алтан эдлэлүүдийн хажууд байсан нь он цагийн хувьд зөрчилтэй байв. Судлаачид эдгээр эдлэлийг хүдрээс бус, солирын төмрөөр хийсэн байж магадгүй хэмээн таамаглажээ.

Салвадор Ровира-Ллоренс тэргүүтэй эрдэмтэд масс-спектрометрийн шинжилгээгээр уг олдворуудын найрлага дахь төмөр болон никелийн харьцааг судалсан байна. Шинжилгээний дүн нь уг эдлэлүүд солирын төмөр ашиглан бүтээгдсэн байх магадлал өндөр болохыг харуулжээ. Хэрэв энэ нь батлагдвал эдгээр нь Иберийн хойг дахь солирын төмрөөр хийсэн анхны олдворууд болох юм.

Гэсэн хэдий ч олдворуудын гадаргуугийн зэврэлт их байгаа нь шинжилгээний үр дүнд тодорхой хязгаарлалт үүсгэж байна. Судлаачид уг дүгнэлтийг бүрэн баталгаажуулахын тулд ирээдүйд илүү нарийн, эд зүйлийг гэмтээхгүй шинжилгээний аргуудыг ашиглахыг зөвлөжээ. Эртний Египетийн Тутанхамон хааны булшнаас олдсон төмөр чинжаал зэрэг бусад жишээнүүд нь тухайн үеийн дархчууд солирын төмрийг үнэлж, ашигладаг байсныг нотолдог билээ.

Дэлгэрэнгүйг эх сурвалжаас харах

↓Эх сурвалжийг нээх ↓

In the winter of 1963, workers digging in a gravel pit in southeastern Spain uncovered one of Europe’s richest prehistoric treasures. Gold bowls, bottles and thick bracelets emerged from the ground, many dating back more than 3,000 years. The collection was remarkable for both its size and the sheer amount of gold it contained.

Among the gleaming objects were two pieces that looked distinctly out of place. Dark, cracked and badly corroded, they had little of the visual appeal of the gold surrounding them. For decades, they remained among the least impressive objects in the collection, although their unusual composition would eventually attract scientific interest.

A Fortune in a Gravel Pit

The discovery took place in December 1963 near Villena, a town in the province of Alicante. Workers came across buried metal while excavating gravel, prompting local archaeologist José María Soler to lead an investigation of the site.

The collection became known as the Treasure of Villena and is now housed at the Villena Archaeological Museum. The museum counts 66 objects, although some catalogs list 59. Most were fashioned from sheet gold, amounting to nearly 10 kilograms (22 pounds), with several pieces of silver and amber also included.

The Treasure of Villena. Credit: Villena Museum

Archaeologists have dated the gold to approximately 1500–1200 BC, placing it in the Late Bronze Age. Yet two objects presented an awkward chronological problem. Unlike the gold artifacts, they were made of iron, a metal that was not commonly produced in the region until centuries later.

Two Objects That Didn’t Fit

One of the iron pieces is a torc-like bracelet measuring 8.5 centimeters (3.35 inches) across. The other is a hollow hemisphere, roughly 4.5 centimeters (1.77 inches) wide, decorated with gold. Researchers believe the smaller object may once have formed part of the handle of a sword or ceremonial scepter.

The difficulty lay in the dates. On the Iberian Peninsula, the Iron Age began around 850 BC, when communities started producing iron by smelting ore extracted from the ground. If the Villena objects had been made using that process, their presence alongside much older Bronze Age gold would have been difficult to explain.

Villena Bracelet
The iron bracelet, which measures 8.5 centimeters (3.35 inches) across. Credit: Villena Museum

There was, however, another possible source of iron. Certain meteorites contain naturally occurring metallic iron, which can be worked without first extracting it from ore. Ancient metalworkers could therefore have used iron long before conventional smelting techniques reached their communities.

The Nickel Test

Iron meteorites consist primarily of iron mixed with nickel, usually at concentrations considerably higher than those found in iron produced from terrestrial ores. That chemical distinction gives scientists a way to investigate where an ancient metal artifact originated, even when its appearance offers few clues.

Six decades after the Villena discovery, Salvador Rovira-Llorens, the retired head of conservation at Spain’s National Archaeological Museum, joined Ignacio Montero Ruiz and Martina Renzi to examine the two objects. With permission from the museum, the researchers removed small samples from the bracelet and hemisphere and analyzed their composition using mass spectrometry.

The results indicated that both objects contained iron and nickel in proportions consistent with meteoritic iron. Corrosion had substantially altered their surfaces, complicating the analysis, but the chemical evidence supported the possibility that the metal had originated in a meteorite rather than terrestrial ore.

Villena Hemisphere
The iron-and-gold hemisphere, which has a maximum diameter of 4.5 centimeters (1.77 inches). Credit: Villena Museum

In their paper, published in Trabajos de Prehistoria, the researchers concluded that the cap and bracelet “would currently be the first two pieces attributable to meteoritic iron in the Iberian Peninsula.” They placed the objects between approximately 1400 and 1200 BC, consistent with the age of the surrounding gold artifacts.

The findings offer a plausible explanation for why iron appeared in a treasure dating from centuries before the regional Iron Age. The researchers nevertheless emphasized the limitations caused by corrosion and recommended further examination using newer non-invasive analytical techniques.

Metal From the Sky

In Late Bronze Age Western Europe, metalworking revolved around copper and bronze, with iron smelting still largely unknown. Metallic iron recovered from meteorites was exceptionally uncommon, and objects made from it could be valued alongside precious materials such as gold and silver.

A particularly well-known example is the iron dagger discovered in the tomb of Tutankhamun in Egypt. Analysis has shown that the weapon was forged from meteoritic iron. Other Bronze Age weapons and ornaments made from the same material have been identified around the eastern Mediterranean, providing evidence that ancient craftspeople recognized and worked this unusual metal.

The Villena bracelet and cap now appear to belong to that small group of artifacts. Both stand apart from the predominantly gold collection, not simply because of their appearance, but because the iron used to make them may have arrived on Earth naturally rather than being extracted through smelting.

Locationofstrangemetalsalicante
Location of the Villena Treasure (Alicante) in the Iberian Peninsula. Credit: Rovira-Llorens et al./ Trabajos de Prehistoria

Their unusual character had been apparent since the original excavation. Field records from 1963 described a heavy, leaden metal concealed beneath a cracked layer of oxide. At the time, the description offered little indication of the objects’ possible origin, and it would take roughly six decades before laboratory analysis provided a possible answer.

The results are not yet definitive, particularly given the extensive corrosion affecting both pieces. Further testing may establish whether their nickel content truly reflects meteoritic material, but the evidence already suggests that two of the most unassuming objects in one of Europe’s greatest prehistoric gold hoards could have been fashioned from iron that fell from the sky.

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